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Sponsor Details

Name
Sulfate additive studies to reduce methane emissions from livestock manure
Description
Canadian livestock farmers are interested in reducing the carbon footprint of their products. Reducing methane emissions is a key part of this goal, and manure is a significant methane source. Technologies such as biogas can reduce emissions, however, these systems have high capital costs and require permits and grid connections. This study explores low-cost alternatives which could help the industries reduce emissions in the near-term. Previous studies have shown that H2SO4 is an effective additive to suppress methane emissions, linked to its strong acidity and sulfate ion species. This study compares the additive efficacy between a sulfate-based non-acid (CaSO4), and two rates of acidification, one at pH>7 and one at pH<7, for a sulfate-based acid (H2SO4) and a sulfate-free acid (H3PO4). The efficiency gain in suppression from CaSO4 at different treatment rates was also analyzed. Two mechanisms of suppression were observed: acidification had a strong effect within 40 days (up to 65% for H2SO4, and 54% for H3PO4), possibly related to the bacterial growth phase, while sulfate compounds were found to reduce methane emission more effectively after 50 days, with cumulative suppression of up to 63% for CaSO4 and 91% for H2SO4 after 157 days. These results suggest that multiple additives can be successful at mitigation, and suggest further development of affordable and modular strategies - harnessing these mechanisms - can unlock effective near-term solutions for small and medium producers to make large reductions in methane in the near-term.
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